Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the, ACD/Labs Percepta Platform - PhysChem Module, Compounds with the same molecular formula, Search Google for structures with same skeleton, DANGER: POISON, irritates skin, eyes, lungs. O.O.O.O.O.O.[Cl-].[Cl-]. Nickel(II) Chloride 6-hydrate pure Quality Name: pure Specifications: Assay (Compl. CopyCopied, LAIZPRYFQUWUBN-UHFFFAOYSA-L [Ni+2]  The dme ligands in this complex are labile. In some derivatives, the chloride remains within the coordination sphere, whereas chloride is displaced with highly basic ligands. Terms & Conditions. ChEBI CHEBI:53542 Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module Molecular weight calculation: 58.6934 + 35.453*2 + 6*(1.00794*2 + 15.9994) ›› Percent composition by element A hydrate of nickel chloride containing nickel (in the +2 oxidation state), chloride and water moeities in the ratio 1:2:6. This reagent also promotes homo-coupling reactions, that is 2RX → R-R where R = aryl, vinyl. PRODUCT AVAILABILITY: Did you know you can view a product's availability right on the product page? As a mild Lewis acid, e.g. , NiCl2-dme (or NiCl2-glyme) is used due to its increased solubility in comparison to the hexahydrate..
1967. volume 23, pp. "Nickel metal and other compounds (as Ni)", National Institute for Occupational Safety and Health, "Evidence of carcinogenicity in humans of water-soluble nickel salts", "Practical Ni-Catalyzed Aryl–Alkyl Cross-Coupling of Secondary Redox-Active Esters", https://en.wikipedia.org/w/index.php?title=Nickel(II)_chloride&oldid=983062444, Creative Commons Attribution-ShareAlike License.
Linstrom, Peter J.; Mallard, William G. Synonym(s): (nickel(II) chloride, hexahydrate), MSDS We Believe You Are Important, How Can We Help? Nickel chloride solutions are used for electroplating nickel onto other metal items. CopyCopied, CSID:23047, http://www.chemspider.com/Chemical-Structure.23047.html (accessed 13:31, Nov 5, 2020) Simply enter the quantity you want to purchase and the current availability will appear below the item. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module. In the presence of water scavengers, hydrated nickel(II) chloride reacts with dimethoxyethane (dme) to form the molecular complex NiCl2(dme)2. 6H2O can be used to form a variety of nickel coordination complexes because the H2O ligands are rapidly displaced by ammonia, amines, thioethers, thiolates, and organophosphines. 6H 2 O is green. Don't have a web profile? For example, this complex reacts with sodium cyclopentadienide to give the sandwich compound nickelocene. (eds. 2001 J. Wiley & Sons, New York. Square planar complexes of nickel can often form five-coordinate adducts. Create one now. In a hurry? for the regioselective isomerization of dienols: For selective reductions in the presence of. As a catalyst for making dialkyl arylphosphonates from phosphites and. Nickel(II) chloride, in various forms, is the most important source of nickel for chemical synthesis. Tien-Yau Luh, Yu-Tsai Hsieh Nickel(II) Chloride" in Encyclopedia of Reagents for Organic Synthesis (L. A. Paquette, Ed.) For example, NiCl2(PPh3)2, containing four-coordinate Ni(II), exists in solution as a mixture of both the diamagnetic square planar and the paramagnetic tetrahedral isomers. Polymeric raw materials (granulates) Ancillary polymer products; Technical polymers and plastics Hexammine nickel chloride complex is soluble when respective cobalt complex is not, which allows for easy separating of these close-related metals in laboratory conditions. Nickelous Chloride, 6-Hydrate, Crystal, BAKER ANALYZED Reagent. Illustrative complexes include: Some nickel chloride complexes exist as an equilibrium mixture of two geometries; these examples are some of the most dramatic illustrations of structural isomerism for a given coordination number. ); This page was last edited on 12 October 2020, at 01:07.
C of A, ©Thomas Scientific 2020 All Rights Reserved. Prolonged inhalation exposure to nickel and its compounds has been linked to increased cancer risk to the lungs and nasal passages. , Nickelous chloride, nickel(II) salt of hydrochloric acid, Except where otherwise noted, data are given for materials in their. Nickel(II) chloride is irritating upon ingestion, inhalation, skin contact, and eye contact. What is the chemical Formula of nickel chloride dihydrate? NiCl2 and its hydrate are occasionally useful in organic synthesis. I am trying to balance the chemical equation for this reaction, but I'm not sure of the chemical formula for nickel chloride dihydrate is. ›› Nickel(II) Chloride Hexahydrate molecular weight. NiCl2 is the precursor to acetylacetonate complexes Ni(acac)2(H2O)2 and the benzene-soluble (Ni(acac)2)3, which is a precursor to Ni(1,5-cyclooctadiene)2, an important reagent in organonickel chemistry. NiCl2 with or plus 2H20 or something? Formula: NiCl 2 •6H 2 O Formula Weight: 237.71 CAS Number: 7791-20-0 Synonym(s): (nickel(II) chloride, hexahydrate) B. Morosin "An X-ray diffraction study on nickel(II) chloride dihydrate" Acta Crystallogr. 630-634. As a precursor to finely divided Ni by reduction with Zn, for the reduction of aldehydes, alkenes, and nitro aromatic compounds. CopyCopied, InChI=1S/2ClH.Ni.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2 A hydrate of nickel chloride containing nickel (in the +2 oxidation state), chloride and water moeities in the ratio 1:2:6. Chemical reaction: Heating solid nickel chloride dihydrate yields solid nickel chloride and water vapor Convert grams Nickel(II) Chloride Hexahydrate to moles or moles Nickel(II) Chloride Hexahydrate to grams.